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Grade C
When a
voltage is applied across a conductor, a force field called an
electric field is set up. The positive side of the field pulls
the electrons along, while the negative side of the field pushes them.
It's a bit like a train with an engine at each end.
The
battery in effect acts as an electron pump and voltage is the
"electrical pressure" from the pump.
A
metal can be thought of as a lattice of ions in a sea of free
electrons. The electrons move randomly and collide with
the metal ions as in the picture below.

The
metal ions are vibrating. All materials vibrate with
temperature; the hotter the temperature, the more they vibrate.
The
ions still have electron shells that surround the nucleus.
The nucleus is very small, about 1/10 000 the size of the atom.
Although most of the atom is empty space, the electrons cannot penetrate
the electron shells. Since the free electrons have the same
negative charge as the electrons in the cloud, the two like charges
repel. The electrons bounce off.
As
they bounce off, the electrons put a tiny little bit of energy
into the ions, which makes them vibrate even more. Therefore the
temperature goes up. Therefore there is more chance of a
collision. So the overall flow of electrons is reduced.
In
insulators, almost all the electrons are bound, so there are very
few electrons to carry the charge. Insulators have a very high
resistance.
In
semi-conductors, the electrons are bound, but can be released into
what's called the conduction band. We won't go into detail
here.
In a
super-conductor, the materials have a very low resistance at very
low temperatures. So big currents can be carried, although a lot
of energy is needed to keep the wires cold.
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